ReviewLipids1996
Epoxy allylic carbocations as conceptual intermediates in the biogenesis of diverse marine oxylipins.
Review in Lipids, 1996. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Some Biogenetic Considerations Regarding the Marine Natural Product (-)-Mucosin.Molecules (Basel, Switzerland) · 2019Article
- ALLENE OXIDE SYNTHASE and HYDROPEROXIDE LYASE, Two Non-Canonical Cytochrome P450s inInternational journal of molecular sciences · 2019Review
- Formation and Cleavage of C-C Bonds by Enzymatic Oxidation-Reduction Reactions.Chemical reviews · 2018Review
- Stereopermutation on the Putative Structure of the Marine Natural Product Mucosin.Molecules (Basel, Switzerland) · 2017Article
- Article
- Biologically Active Oxylipins from Enzymatic and Nonenzymatic Routes in Macroalgae.Marine drugs · 2016Review
- Synthesis of the 16S,17S-Epoxyprotectin Intermediate in the Biosynthesis of Protectins by Human Macrophages.Journal of natural products · 2015Article
- Quantification of selected endogenous hydroxy-oxylipins from tropical marine macroalgae.Marine biotechnology (New York, N.Y.) · 2014Article
- Synthesis of a bicyclobutane fatty acid identified from the cyanobacterium Anabaena PCC 7120.Angewandte Chemie (International ed. in English) · 2011Article
- Mechanistic aspects of CYP74 allene oxide synthases and related cytochrome P450 enzymes.Phytochemistry · 2009Review
- Evidence for an ionic intermediate in the transformation of fatty acid hydroperoxide by a catalase-related allene oxide synthase from the Cyanobacterium Acaryochloris marina.The Journal of biological chemistry · 2009Article
- An update on products and mechanisms of lipid peroxidation.Molecular nutrition & food research · 2009Article
- Enzymatic synthesis of a bicyclobutane fatty acid by a hemoprotein lipoxygenase fusion protein from the cyanobacterium Anabaena PCC 7120.Proceedings of the National Academy of Sciences of the United States of America · 2007Article
- Divinyl ether fatty acid synthesis in late blight-diseased potato leaves.The Plant cell · 1999Article
- Novel oxylipins from the temperate red alga Polyneura latissima: evidence for an arachidonate 9(S)-lipoxygenase.Lipids · 1997Article
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Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Marine organisms, especially marine algae, are extremely rich in a diversity of novel oxylipin structures. Many of these oxylipins contain functionalities and rings of a type and location unknown in mammalian systems. In this perspective reviewing marine oxylipins, a proposal is formulated for the central intermediacy of an epoxy allylic carbocation in the biogenesis of these diverse structures. This proposal is strengthened by the relatively large number of examples which are consistent with this type of mechanistic transformation.
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Registered trials
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