Evidence map›Paper›PMID 42899500›Full record

ArticleChemSusChem2026

Synergistic d-Orbital Interactions and Interfacial Coupling in Metal-Organic Framework-Based Electrocatalysts for Direct Seawater Electrolysis.

Sofiu Mahmud, Hafiz Adil Qayyum, Sharafadeen Gbadamasi, Muhammad Waqas Khan, Suraj Loomba, Muhammad Haris, Chamali Malaarachchi, Seyed Mousavi, Babar Shabbir, Jian Xian and 1 more

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Article in ChemSusChem, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Sofiu MahmudSchool of Engineering, RMIT University, Melbourne, Victoria, Australia.
Hafiz Adil QayyumDepartment of Physics, College of General Studies, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia.ORCID https://orcid.org/0000-0002-9063-9152
Sharafadeen GbadamasiSchool of Sciences, RMIT University, Melbourne, Victoria, Australia.ORCID https://orcid.org/0000-0002-8071-9247
Muhammad Waqas KhanSchool of Sciences, RMIT University, Melbourne, Victoria, Australia.ORCID https://orcid.org/0000-0003-1104-3527
Suraj LoombaSchool of Sciences, RMIT University, Melbourne, Victoria, Australia.
Muhammad HarisSchool of Sciences, RMIT University, Melbourne, Victoria, Australia.
Chamali MalaarachchiSchool of Sciences, RMIT University, Melbourne, Victoria, Australia.
Seyed MousaviSchool of Engineering, RMIT University, Melbourne, Victoria, Australia.
Babar ShabbirSchool of Sciences, RMIT University, Melbourne, Victoria, Australia.ORCID https://orcid.org/0000-0002-8162-8013
Jian XianSchool of Materials and Energy, University of Electronic Science and Technology of China, Chengdu, China.ORCID https://orcid.org/0000-0002-9955-1704
Nasir MahmoodSchool of Engineering, RMIT University, Melbourne, Victoria, Australia.ORCID https://orcid.org/0000-0002-8340-1058

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The structural versatility of metal-organic frameworks (MOFs) makes them attractive platforms for electrocatalyst design, but with limited active site density. Here, Fe-MOF is decorated with Ni-, Mo-, and W-based oxides via electrochemical deposition, avoiding high-temperature carbonization. The short interlayer distances (1.88-2.67 Å) and more negative binding energies (-4.09 to -4.88 eV) indicate intimate interfacial contact and strong adhesion between the deposited metal oxides and the Fe-MOF. Synergistic interactions between Ni 3d and Mo/W non‑3d orbitals modulate electronic structure and optimize adsorption of reaction intermediates. Electron localization values <0.5 and charge density difference analysis reveal substantial electron redistribution and interfacial charge transfer. DFT studies show that NiMoW@Fe-MOF with the lowest ɳ

Indexed as

chlorine evolution reactiondirect seawater splittinghydrogen evolution reactionmetal–organic frameworksoxygen evolution reactiontwo‐dimensional (2D) interface

Identifiers

PMID42899500
PMCPMC13681737

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.