ArticleMaterials and structures2026
Dissolution, diffusion, and precipitation of Mg
Article in Materials and structures, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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7 authors.
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Abstract
Magnesia-based cements (MBCs) are promising low-carbon alternatives to conventional portland cement due to their lower calcination temperature requirements and ability to utilize magnesia derived from carbon-free feedstocks. Understanding these systems requires deep knowledge of the entire reaction sequence: from the initial dissolution of magnesia (MgO) particles and the transport of magnesium ions through solution, to the precipitation of brucite [Mg(OH)₂], and ultimately of binding phases such as magnesium silicate hydrates (M-S-H) or magnesium carbonates. While these reaction steps resemble those in CaO-based systems, fundamental differences in thermodynamic and kinetic behaviors result in key differences in the dissolution and precipitation pathways of MBCs. To further explicate these differences, this review utilizes thermodynamic simulations revealing the effect of chemical additives (complexing ligands) on the solubility of Mg(OH) Supplementary Information: The online version contains supplementary material available at https://doi.org/10.1617/s11527-026-03048-x.
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