ArticleMolecules (Basel, Switzerland)2026
Anti-Markovnikov Hydroamination of Vinylpyridines via a Novel Photocatalytic Strategy.
Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
In this paper, we report a novel photocatalytic strategy for hydroamination reactions under mild conditions of room temperature and air atmosphere, in which commercially available tribromomethylphenyl sulfone (TBMS) efficiently drives the highly selective anti-Markovnikov hydroamination of vinylpyridines with diverse aromatic amines under ultraviolet light irradiation. By optimizing the synthetic conditions, moderate to excellent yields were achieved along with good functional group tolerance, and the highest yield of the target product can reach 97%, while aliphatic amines, amines bearing strong electron-withdrawing groups (e.g., -NO
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