ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Dual-Functional Membranes With Interfacial MXene/PFSA Nanoarchitectures for Low Hydrogen Permeation in Water Electrolysis and Reduced Vanadium Ion Crossover in Flow Batteries.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Proton exchange membrane water electrolysis (PEMWE) and vanadium redox flow batteries (VRFBs) suffer from hydrogen and vanadium ion crossover when using conventional perfluorosulfonic acid (PFSA) membranes. Here we report a layer-by-layer MXene/PFSA membrane architecture in which MXene nanosheets are integrated into PFSA coating layers to create MXene-regulated nanointerfaces that decouple proton conductivity from gas and ion permeation. The lamellar MXene framework introduces tortuous transport pathways and selectively perturbs PFSA hydrophilic domain organization while preserving continuous proton-conducting networks through interfacial hydrogen bonds. As a result, the optimized membrane exhibits simultaneously enhanced H
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