ReviewFrontiers in chemistry2026
Radical 1,2-boron shift in modern organoboron synthesis.
Review in Frontiers in chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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8 authors.
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Abstract
The radical-mediated 1,2-boron shift strategy has emerged as a promising and powerful approach for the construction of functionalized organoboron compounds. This review summarizes and categorizes the relevant studies based on the distinct mechanisms underlying the generation of β-boryl radicals, such as radical addition, oxidative cleavage, decarboxylation reactions, or hydrogen atom transfer (HAT). Furthermore, the reaction scopes, synthetic utilities, and underlying mechanistic pathways are thoroughly examined to provide a comprehensive overview of this evolving strategy.
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