ArticleRSC advances2026
Fluorinated pore walls boost PFAS capture in mechanochemically synthesized covalent organic frameworks.
Article in RSC advances, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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12 authors.
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Abstract
Per- and polyfluoroalkyl substances (PFAS) are persistent water contaminants that require robust, high-affinity sorbents. Covalent organic frameworks (COFs) provide chemically stable, modular platforms for capturing PFAS and mechanochemical synthesis offers an environmentally friendly, scalable method of production. In this study, we use mechanochemistry to quickly produce an isoreticular series of large-pore imine COFs (TAPB-TA, TAPB-DFTA and TAPB-DMTA) with systematically varied pore-wall functionality, which is optimised for PFAS adsorption. The fluorinated TAPB-DFTA COF exhibits the greatest crystallinity, the highest BET surface area (1237 m
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