ArticlePhysical chemistry chemical physics : PCCP2026
Zirconium-free sodium ion conducting NASICON-type structure NaMAl(PO
Article in Physical chemistry chemical physics : PCCP, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Sodium superionic conductors (NASICONs) have shown promising sodium-ion conduction for application in all-solid-state sodium metal batteries. However, many factors hinder their large-scale application, such as high total resistance caused by secondary phases and the formation of zirconia impurities due to sodium oxide volatilisation at elevated temperatures. This work circumvents one of the major impurities by completely removing zirconium from the structure, thereby establishing the concept of zirconium-free NASICON-type materials. Oxides with nominal chemical formulae NaMAl(PO
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