Ultrasonic/microwave-assisted synthesis of organosilicon quaternary ammonium-modified montmorillonite for selective removal of molybdenum from tungstate feed solution.

Yanjin Huang, Chengxiu Wu, Dengxian Liu, Qian Liu, Sili Ren, Wuhui Luo

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Article in Ultrasonics sonochemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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6 authors.

Yanjin HuangJiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Jiangxi University of Science and Technology, Ganzhou 341000, China.

Chengxiu WuJiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Jiangxi University of Science and Technology, Ganzhou 341000, China.

Dengxian LiuJiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Jiangxi University of Science and Technology, Ganzhou 341000, China.

Qian LiuJiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Jiangxi University of Science and Technology, Ganzhou 341000, China.

Sili RenJiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Jiangxi University of Science and Technology, Ganzhou 341000, China.

Wuhui LuoJiangxi Provincial Key Laboratory of Environmental Pollution Prevention and Control in Mining and Metallurgy, Jiangxi University of Science and Technology, Ganzhou 341000, China. Electronic address: luo070221@126.com.

Funding

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6 · The paper itself

Abstract

The selective separation of molybdenum (Mo) from tungsten (W) remains challenging due to their similar chemical properties. In this study, organosilicon quaternary ammonium salts with varying alkyl chain lengths, including methyl, tetradecyl (TD), and octadecyl, were employed to modify montmorillonite (Mt) via a combined ultrasonic/microwave-assisted protocol in different solvent systems for the separation of Mo from W in simulated W-Mo solutions. The results showed that TD-modified Mt prepared in water (W-TD) and cyclohexane (C-TD) exhibited superior adsorption selectivity and amount for MoS

Indexed as

MolybdenumMontmorilloniteOrganosilicon quaternary ammonium saltsSeparation coefficientTungsten

Identifiers

PMID42837976

DOI10.1016/j.ultsonch.2026.108089

PMCPMC13673027

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