ArticleNature nanotechnology2026
Stereochemical origin of potential hysteresis in lithium metal batteries with lithium-rich cation-disordered rocksalt positive electrodes.
Article in Nature nanotechnology, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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22 authors.
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Abstract
Li-rich cation-disordered rocksalts (DRXs) are promising active materials for designing high-capacity positive electrodes for non-aqueous lithium-based batteries. However, the use of DRX-based positive electrodes results in pronounced cell potential hysteresis and low energy efficiency. The reasons for these detrimental behaviours remain unclear owing to the complex structural evolution of DRXs during battery operation. Here, via extensive physicochemical and electrochemical characterizations, we show that multiscale stereochemistry, particularly structure distortion at the atomic scale and short-range ordering in nanoscale domains, can thermodynamically and kinetically affect the potential hysteresis of Li||DRX cells. By using DRX models, we show that redox-inactive d
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