ArticleOrganometallics2026
Flash Communication: Exploring the Coordination of π‑Acids and Redox-Active Diatomics to a High-Spin and Highly Fluorinated Ferrous Compound.
Article in Organometallics, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A new trigonally symmetric ligand scaffold is reported from the reaction of tris-(2-aminoethyl)-amine (TREN) and methyl trifluoroacetate. Deprotonation and metalation with iron-(II) yields a trigonal monopyramidal ferrate that bears an open coordination site surrounded by C-F motifs. The weak-field ligand environment promoted by the fluorinated amidate donors leads to distinctive behaviors that are apparent in reactions with π-acids such as CO and
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