ArticleJACS Au2026
Harnessing Vinyl Cation Reactivity Enables Oxime Ether Formation and an Unusual Base-Promoted Rearrangement to Esters.
Article in JACS Au, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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8 authors.
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Abstract
Harnessing vinyl cation reactivity under controlled conditions remains a longstanding challenge in carbocation chemistry, as the ionization of vinyl triflates and related precursors is often slow, limiting the development of general and selective reaction manifolds involving vinyl cations. Here, we report an aluminum-catalyzed strategy that generates and intercepts vinyl cation intermediates from vinyl triflates, enabling direct access to oxime ethers using readily available nitroalkanes. Oxime ether formation often exhibits a pronounced
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