ArticleNature communications2026
Construction of molecular fans in metal-organic framework to overcome diffusion resistance for trace benzene capture.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Molecular size-matched pores of adsorbents provide strong adsorptive forces for benzene, but high diffusion resistance. Overcoming the diffusion resistance within molecular size-matched pores is essential to efficient capture of trace benzene from indoor air or industrial exhaust gas, but challenging. Herein, we report a stable Fe-based metal-organic framework (ZJU-701) featuring hierarchical micropores (5.8 ± 0.9, 10.2 ± 2.3, and 21.2 ± 1.4 Å) and molecular fans with 1,4-naphthylene as rotors between micropores. ZJU-701 shows adsorption rate constant of 5.84 × 10⁻
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