ArticleNature communications2026
Bromide-mediated paired electrosynthesis of hydrogen and epoxide.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Water electrolysis struggles to compete with the low cost of hydrogen produced from methane or coal. We propose a bromide-mediated paired electrosynthesis system in which an aqueous electrolyte is combined with olefins in an inert organic co-solvent to simultaneously generate hydrogen and epoxides. In this process, bromide electrolysis first produces gaseous hydrogen and solution-confined bromine; the bromine is then used to partially oxidize olefins into high-value epoxides while being regenerated back to bromide. By replacing low-value oxygen with valuable epoxides, this approach increases the economic viability of water electrolysis and can be applied to a wide range of olefins. We demonstrate the concept using styrene, converting water and styrene into hydrogen and styrene oxide in a membraneless system with high efficiency, high rate, and high product selectivity.
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