ArticleBeilstein journal of organic chemistry2026
Silver-catalyzed anionic [3 + 2] cycloaddition of benzyl isocyanides with polyfluoroalkylchromones and pyrones: direct synthesis of 2-arylpyrroles.
Article in Beilstein journal of organic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A silver-catalyzed anionic [3 + 2] cycloaddition of benzyl isocyanides has been developed, providing direct one-pot access to 2-arylpyrroles - a privileged scaffold pervasive in medicinal chemistry and functional materials. Despite high demand, general one-step routes to this motif remain rare, and the synthetic potential of benzyl isocyanides in cycloaddition chemistry has been severely limited by their low reactivity. We herein show that the combination of AgOAc (10 mol %) and KO
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