ArticleThe journal of physical chemistry. C, Nanomaterials and interfaces2026
Ligation of Carbon Monoxide at Iron and Cobalt Single-Metal-Atom Sites: Competition for the +1 Oxidation State in a Surface-Confined Organic Network.
Article in The journal of physical chemistry. C, Nanomaterials and interfaces, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Cobalt coordination to a FeTPyP monolayer on graphene yields a two-dimensional FeTPyP-Co metal-organic network, stabilizing highly reactive Fe-(I) sites within a biomimetic coordination architecture. The assembly process triggers an electronic reorganization that activates the pristine Fe-(II) centers, enabling competitive CO ligation. A thorough synergistic investigation combining
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