Self-Assembling Comb-like Fluorinated Epoxy Acrylates for Low Surface Energy UV-Curable Coatings.

Yejung Lee, Hyesu Jang, Daeun Jeong, Su Bin Ji, Ye Rim Cho, Namhee Kim, Myung Hwa Kim, Yong-Ju Kwon

Abstract read

In one paragraph

Article in Polymers, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

8 authors.

Yejung LeeDepartment of Chemistry, Ewha Womans University, Seoul 03760, Republic of Korea.

Hyesu JangDepartment of Chemistry, Ewha Womans University, Seoul 03760, Republic of Korea.

Daeun JeongDepartment of Chemistry, Seoul Women's University, Seoul 01797, Republic of Korea.

Su Bin JiDepartment of Chemistry, Seoul Women's University, Seoul 01797, Republic of Korea.

Ye Rim ChoDepartment of Chemistry, Seoul Women's University, Seoul 01797, Republic of Korea.

Namhee KimDepartment of Chemistry, Ewha Womans University, Seoul 03760, Republic of Korea.ORCID 0009-0000-1969-4370

Myung Hwa KimDepartment of Chemistry, Ewha Womans University, Seoul 03760, Republic of Korea.

Yong-Ju KwonDepartment of Chemistry, Seoul Women's University, Seoul 01797, Republic of Korea.ORCID 0000-0001-9517-7885

Funding

Seoul Women's University 2025-0242

6 · The paper itself

Abstract

Fluorinated UV-curable coatings typically rely on high fluorine loadings to achieve water repellency, which causes phase separation, high cost, and environmental concerns. Here, a novel UV-curable fluorinated epoxy acrylate (FEA) oligomer with a comb-like architecture bearing perfluorophenyl-terminated fluorinated side chains was synthesized to maximize fluorine efficiency. A mono-substituted fluorinated alcohol was prepared via nucleophilic aromatic substitution of hexafluorobenzene with octafluorohexanediol, and the FEA oligomer was constructed through a two-step urethane-forming reaction with diglycerol diacrylate (DGDA) and isophorone diisocyanate (IPDI). The chemical structures were confirmed by FT-IR and

Indexed as

fluorine efficiencyhydrophobic coatingperfluorophenylphotopolymerizationsurface segregationurethane acrylatewater contact angle

Identifiers

PMID42797168

DOI10.3390/polym18182259

PMCPMC13611117

What OpenQuestion holds

Textmetadata

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.