Evidence map›Paper›PMID 42769857›Full record

ArticleRSC applied interfaces2024

Exploring the influence of mesoporosity in hard carbon-templated hierarchical SAPO-5 for ethanol dehydration.

Matthew E Potter, Evangeline B McShane, Nienke L Visser, Johannes D Meeldijk, Lisa J Allen, Stephen M King, Marina Carravetta, Petra E de Jongh, Bart D Vandegehuchte, Robert Raja

Abstract read
In one paragraph

Article in RSC applied interfaces, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Matthew E PotterUK CatalysisHub, Research Complex at Harwell, Rutherford Appleton Laboratory Didcot OX11 0FA UK mep61@bath.ac.uk.ORCID https://orcid.org/0000-0001-9849-3306
Evangeline B McShaneSchool of Chemistry, University of Southampton Highfield Campus Southampton SO17 1BJ UK.ORCID https://orcid.org/0000-0002-5935-8328
Nienke L VisserMaterials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands.ORCID https://orcid.org/0000-0003-1027-2299
Johannes D MeeldijkMaterials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands.
Lisa J AllenUK CatalysisHub, Research Complex at Harwell, Rutherford Appleton Laboratory Didcot OX11 0FA UK mep61@bath.ac.uk.ORCID https://orcid.org/0000-0003-2480-3804
Stephen M KingISIS Neutron and Muon Source, STFC Rutherford Appleton Laboratory Harwell Campus Didcot OX11 0QX UK.ORCID https://orcid.org/0000-0003-3386-9151
Marina CarravettaSchool of Chemistry, University of Southampton Highfield Campus Southampton SO17 1BJ UK.ORCID https://orcid.org/0000-0002-6296-2104
Petra E de JonghMaterials Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University Universiteitsweg 99 3584 CG Utrecht The Netherlands.ORCID https://orcid.org/0000-0002-2216-2620
Bart D VandegehuchteTotalEnergies, OneTech Belgium Zone Industrielle Feluy C B-7181 Seneffe Belgium.
Robert RajaSchool of Chemistry, University of Southampton Highfield Campus Southampton SO17 1BJ UK.ORCID https://orcid.org/0000-0002-4161-7053

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Microporous solid acid catalysts offer a vast amount of control over chemical processes. However, their coveted smaller pores also have several drawbacks, including a limited substrate scope, faster deactivation, and pore blockage. As such, there are significant advantages to introducing mesopores alongside the microporous framework, to create hierarchically porous frameworks. This work explores the influence of adapting our microporous synthetic procedure for silicoaluminophosphate (SAPO-5) to include different shaped carbon nanotemplates. The differing size of the mesopores formed is explored using nitrogen physisorption, transmission electron microscopy and small angle neutron scattering. In this work, we uniquely use small angle neutron scattering for probing hierarchical silicoaluminophosphates synthesised with hard templating methods. Here small angle neutron scattering was able to probe the shape and size of the mesopores and link their accessibility to their catalytic performance.

Identifiers

PMID42769857
PMCPMC13591374

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.