ArticleBeilstein journal of organic chemistry2026
A study towards the undirected fluorination and chlorination of cubane 1,4-diester.
Article in Beilstein journal of organic chemistry, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
A study towards the undirected C-H fluorination and chlorination of cubane 1,4-diester is described using a user-friendly reagent such as Selectfluor and 1,3-dichloro-5,5-dimethylhydantoin under photoinduction. While the fluorocubane 1,4-diester is formed in low yield (8% yield) due to loss of material, the chlorocubane 1,4-diester was on the other hand prepared in 59% yield without the need for any photocatalyst. Moreover, a proof-of-concept of the chlorination of this strained scaffold was demonstrated using flow technology.
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