ArticleChemical science2026
Access to and unexplored reactivity of nickel-bound 5-membered O- and N-heterocyclic arynes
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
N-Heterocyclic arynes are versatile but underutilized intermediates for rapidly functionalizing N-containing arenes. Part of the reason for the underutilization of N-heterocyclic arynes is that 5-membered N-heterocyclic arynes are inaccessible due to ring strain. In 2024, our group demonstrated that coordinating such strained intermediates to a metal center could stabilize the aryne bond
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