Benzimidazole-Regulated 1D 4-Fluorosalicylic Acid MOF Composite Material Design and Its Application in Glucose Sensing.

Haixia Wu, Dianheng Yu, Jinliang Hu, Fang Wang, Songtao Zhang, Kailu Guo, Huan Pang

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Haixia WuHenan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China.

Dianheng YuTesting Center, School of Chemistry and Materials, Yangzhou University, Yangzhou 225009, China.

Jinliang HuTesting Center, School of Chemistry and Materials, Yangzhou University, Yangzhou 225009, China.

Fang WangTesting Center, School of Chemistry and Materials, Yangzhou University, Yangzhou 225009, China.

Songtao ZhangTesting Center, School of Chemistry and Materials, Yangzhou University, Yangzhou 225009, China.

Kailu GuoHenan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China.

Huan PangTesting Center, School of Chemistry and Materials, Yangzhou University, Yangzhou 225009, China.ORCID 0000-0002-5319-0480

Funding

Key Basic Research Program of Jiangsu (Yangzhou) Province BK20253046National Natural Science Foundation of China 52371240Priority Academic Program Development of Jiangsu Higher Education InstitutionsState Key Laboratory of Materials-Oriented Chemical Engineering No. SKL-MCE-25B09Yangzhou Innovation Capability Enhancement Fund/program SCX2025020017

6 · The paper itself

Abstract

Metal-organic frameworks (MOFs) have significant potential in electrochemical sensors, but the guest molecules and residual solvents in the pores often block the active sites and limit the reaction kinetics. One-dimensional nanostructures can provide direct conduction pathways and shorten ion diffusion distances, thereby enhancing electron transport and electrode contact. Meanwhile, fluorine-incorporated MOF materials leverage the high electronegativity of fluorine to substitute oxygen, suppress oxidation to widen the voltage window, and improve stability through enhanced hydrophobicity. In this work, 4-fluorosalicylic acid (4FSA) was used as the ligand and benzimidazole (Bim) was introduced to adjust the coordination environment, and one-dimensional Bim4FSA-MOF nanorods were successfully constructed. While the guest molecules were largely removed, the nickel sites were thereby activated and the pore size was enlarged. Due to the synergistic effect of one-dimensional nanostructure-promoted electron transport and the Ni(OH)

Indexed as

electrochemical sensorglucosemetal–organic frameworksnickel-based materialsone-dimensional nanostructure composites

Identifiers

PMID42738755

DOI10.3390/molecules31173096

PMCPMC13567323

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.