ArticleNano-micro letters2026
Polyhydroxy Molecular Regulator Enabled Interfacial Microenvironment Programming for Alkaline Zinc-Iron Flow Batteries.
Article in Nano-micro letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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10 authors.
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Abstract
Alkaline zinc-iron flow batteries (ZIFBs) are attractive for large-scale energy storage because of their low cost, intrinsic safety, and scalable architecture, yet their practical deployment remains hindered by hydrogen evolution and uncontrolled Zn deposition in three-dimensional porous electrodes. Here, we report that isomalt acts as a polyhydroxy molecular regulator that reconfigures the interfacial microenvironment of porous carbon felt, thereby endowing the porous electrode with a more deposition-directing function for reversible Zn plating/stripping. In the bulk electrolyte, isomalt reconstructs the local hydrogen-bond network, lowers water activity, and suppresses hydrogen evolution. At the carbon/electrolyte interface, its preferential lateral adsorption establishes a hydroxyl-rich interphase that homogenizes zincate transport and directs Zn growth toward a preferred (002) orientation, thus promoting compact and reversible deposition. This interfacial microenvironment programming markedly reduces the charge-transfer resistance and activation barrier of the Zn anode, enabling stable cycling for over 500 cycles at 20 mA cm
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