Evidence map›Paper›PMID 42730106›Full record

ArticleACS omega2026

Practical Ni-Catalyzed Synthesis of Allylic Boronates.

Elena M Rafetzeder, Ziyi Quan, Emily A York, Scott E Schaus

Abstract read
In one paragraph

Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Elena M RafetzederDepartment of Chemistry, Center for Molecular Discovery, Life Science and Engineering Building, Boston University, 24 Cummington Mall, Boston, Massachusetts 02215, United States.ORCID https://orcid.org/0009-0006-4161-0990
Ziyi QuanDepartment of Chemistry, Center for Molecular Discovery, Life Science and Engineering Building, Boston University, 24 Cummington Mall, Boston, Massachusetts 02215, United States.
Emily A YorkDepartment of Chemistry, Center for Molecular Discovery, Life Science and Engineering Building, Boston University, 24 Cummington Mall, Boston, Massachusetts 02215, United States.
Scott E SchausDepartment of Chemistry, Center for Molecular Discovery, Life Science and Engineering Building, Boston University, 24 Cummington Mall, Boston, Massachusetts 02215, United States.ORCID https://orcid.org/0000-0002-5877-6587

Funding

Advancement of poxvirus inhibitorR01AI151559 · NIAID · BOSTON UNIVERSITY MEDICAL CAMPUS · PI BROWN, LAUREN ELAINE, CONNOR, JOHN H · 2020 to 2025
$5.8M
Targeting the Genus Leishmania with Small MoleculesR01AI151639 · NIAID · BOSTON UNIVERSITY (CHARLES RIVER CAMPUS) · PI BROWN, LAUREN ELAINE, SCHAUS, SCOTT EDWARD · 2021 to 2025
$3.8M
The Design and Implementation of Asymmetric Organocatalysis in SynthesisR01GM078240 · NIGMS · BOSTON UNIVERSITY (CHARLES RIVER CAMPUS) · PI SCHAUS, SCOTT EDWARD · 2007 to 2018
$2.9M
NIAID NIH HHS R01 AI151559NIAID NIH HHS R01 AI151639NIGMS NIH HHS R01 GM078240
6 · The paper itself

Abstract

Two nickel-catalyzed protocols for the borylation of allylic acetates have been developed, enabling direct and efficient access to allylic boronates under operationally simple conditions. Both transformations are setup on the benchtop, employing commercially available Ni catalysts in combination with readily accessible boron reagents. The methods exhibit broad functional group tolerance and substrate generality, as demonstrated across 28 examples, delivering the corresponding allylic boronates in isolated yields of up to 93%. Notably, gram-scale reactions proceed with comparable efficiency, underscoring the scalability and synthetic utility of the approach.

Identifiers

PMID42730106
PMCPMC13563615

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.