Article3D printing and additive manufacturing2026
Metal Organic Framework-Enhanced 3D-Printed Monoliths for Water Filtration: Tackling Structural Integrity with Higher Adsorption.
Article in 3D printing and additive manufacturing, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Access to clean water remains unattainable due to water pollution caused by various sources. Conventional water purification methods fall short of eliminating micro-sized and soluble contaminants, promoting the exploration of innovative approaches utilizing nanomaterials. Thus, metal-organic frameworks (MOFs) have attained considerable attention for water filtration, exhibiting high pollutant adsorption potential due to their abundant and well-organized nanoporous structure. However, a major limitation of MOFs is secondary contamination arising from MOFs leaching and detaching from the substrate on which they are synthesized. Herein, we propose a novel design and manufacturing of MOF-laden monolith 3D structure (MLMS) to minimize such drawbacks. Using extrusion-based additive manufacturing, we constructed the MLMS with macroscale porosity, employing a Moiré pattern to enhance its mechanical strength in different dynamic fluid conditions. Copper-based MOFs (Cu-MOFs) were integrated within the MLMS with high adhesion by the introduction of heat treatment, thereby minimizing leaching and detaching while maintaining the pollutant absorption capability. Furthermore, the Cu-MOFs' growth, distribution, and adsorption efficiencies have been studied by growing them on various commercially available 3D printing polymers [polylactic acid, polyethylene terephthalate glycol (PETG), acrylonitrile butadiene styrene, and thermoplastic polyurethane]. The results show that the surface area covered by the MOFs ranges from 12.8% to 75.8% depending on the number synthesis cycle. In addition, a reduced leaching rate of 16.1% from the MLMS was observed at a high-water flux (4.14 × 10
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