Evidence map›Paper›PMID 42713521›Full record

ArticleChemical science2026

Tuning chiroptical properties and device hyperfluorescence efficiency

Mahni Fatahi, Yan Xu, Dongyang Chen, Praveen Choudhary, Jhon Sebastian Oviedo Ortiz, Jasmin Seibert, Stefan Bräse, Jeanne Crassous, Xiao-Hong Zhang, Eli Zysman-Colman

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Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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2 · The registry

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3 · Its place in the literature

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4 · The record

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5 · Who and what money

Authors and funding

10 authors.

Mahni FatahiOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews St Andrews KY16 9ST UK eli.zysman-colman@st-andrews.ac.uk.ORCID https://orcid.org/0000-0003-4874-0246
Yan XuOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews St Andrews KY16 9ST UK eli.zysman-colman@st-andrews.ac.uk.
Dongyang ChenOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews St Andrews KY16 9ST UK eli.zysman-colman@st-andrews.ac.uk.
Praveen ChoudharyOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews St Andrews KY16 9ST UK eli.zysman-colman@st-andrews.ac.uk.ORCID https://orcid.org/0000-0002-1291-0832
Jhon Sebastian Oviedo OrtizUniversity of Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226 F-35000 Rennes France jeanne.crassous@univ-rennes.fr.
Jasmin SeibertInstitute of Organic Chemistry (IOC), Karlsruhe Institute of Technology (KIT) Kaiserstraße 12 76131 Karlsruhe Germany.ORCID https://orcid.org/0000-0003-2869-350X
Stefan BräseInstitute of Organic Chemistry (IOC), Karlsruhe Institute of Technology (KIT) Kaiserstraße 12 76131 Karlsruhe Germany.ORCID https://orcid.org/0000-0003-4845-3191
Jeanne CrassousUniversity of Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226 F-35000 Rennes France jeanne.crassous@univ-rennes.fr.ORCID https://orcid.org/0000-0002-4037-6067
Xiao-Hong ZhangInstitute of Functional Nano & Soft Materials (FUNSOM), Joint International Research Laboratory of Carbon-Based Functional Materials and Devices, Soochow University Suzhou Jiangsu 21523 P. R. China xiaohong_zhang@suda.edu.cn.ORCID https://orcid.org/0000-0002-6732-2499
Eli Zysman-ColmanOrganic Semiconductor Centre, EaStCHEM School of Chemistry, University of St Andrews St Andrews KY16 9ST UK eli.zysman-colman@st-andrews.ac.uk.ORCID https://orcid.org/0000-0001-7183-6022

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Multi-resonant thermally activated delayed fluorescence (MR-TADF) emitters offer an attractive solution for the fabrication of colour-saturated organic light-emitting diodes (OLEDs). Still, their rigid frameworks often lead to slow reverse intersystem crossing and aggregation-caused quenching. To address these challenges and simultaneously introduce chiroptical properties in solution-processable materials, here we present the first examples of chiral intramolecular Förster resonance energy transfer (FRET) MR-TADF dendrimers, CzPBN-CzBN and CzPBA-CzBN. These emitters combine an MR-TADF core with chiral paracyclophane (CzP)-based donor dendrons linked to different acceptor units, benzonitrile for CzPBN-CzBN and benzoic acid for CzPBA-CzBN. While both dendrimers show narrowband TADF emission, the nature of the acceptor impacts their chiroptical properties. Specifically, CzPBA-CzBN exhibits circularly polarised luminescence (CPL), whereas CzPBN-CzBN does not due to a weaker circular dichroism signal. Conversely, in solution-processed hyperfluorescent (HF) OLEDs, the device with CzPBN-CzBN achieved a superior maximum external quantum efficiency (EQE

Identifiers

PMID42713521
PMCPMC13552525

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