ArticleNational science review2026
A step-channel gel polymer electrolyte for solid-state sodium batteries.
Article in National science review, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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16 authors.
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Abstract
Gel polymer electrolytes (GPEs) paired with abundant sodium (Na) and high-voltage polyanionic cathode, offer improved energy density and superior safety, positioning them as scalable alternatives for resource-limited lithium batteries. However, such technologies are plagued by critical interfacial engineering challenges: existing GPEs fail to sustain (electro)-chemical stability and mechanical close contact at high-loading cathodes and highly reactive anodes. Here, we report a rationally engineered GPE featuring biphasic polymer, creating step channels and polymer-solvent dipole adsorption to address the key issues. It enables volume-constrained bidirectional transport of infilling linear ether and cyclic carbonate solvents and endows the polymer with differential mechanical viscoelasticity for high-loading cathodes and ductile Na anodes. Therefore, a high-energy-density full cell of Na||Na
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