ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Asymmetric Fluorinated Spiro Hole-Transport Materials Enabled by a Rapid Core-Forming Strategy for Blade-Coated Perovskite Solar Cells.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Developing hole-transporting materials (HTMs) that simultaneously enable high efficiency, stability, and scalable processing remains a key challenge for perovskite solar cells (PSCs). Here, we report the facile synthesis of asymmetric fluorinated spiro-type HTMs that integrate molecular design with scalable fabrication. The controlled incorporation and positioning of fluorine within a common asymmetric molecular framework tune the energy levels, solid-state organization, and interfacial interactions of the HTMs. Coupling these materials with a fully blade-coating-based fabrication process and vacuum-assisted crystallization enables controlled film formation, yielding uniform, compact films with reduced defect density. As a result, PSCs based on the optimized HTM achieve a PCE of 24.49%, maintaining 23.28% for large-area (1.00 cm
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