Organocatalytic asymmetric electrochemical synthesis of epibromohydrins from allylic alcohols.

Zhengyu Han, Ming Fang, Peinan Shang, Shuxuan Liu, Hai Huang, Jianwei Sun

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Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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6 authors.

Zhengyu HanJiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University Changzhou 213164 China huanghai@cczu.edu.cn hanzhengyu@cczu.edu.cn.

Ming FangJiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University Changzhou 213164 China huanghai@cczu.edu.cn hanzhengyu@cczu.edu.cn.

Peinan ShangJiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University Changzhou 213164 China huanghai@cczu.edu.cn hanzhengyu@cczu.edu.cn.

Shuxuan LiuJiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University Changzhou 213164 China huanghai@cczu.edu.cn hanzhengyu@cczu.edu.cn.

Hai HuangJiangsu Key Laboratory of Advanced Catalytic Materials & Technology, School of Petrochemical Engineering, Changzhou University Changzhou 213164 China huanghai@cczu.edu.cn hanzhengyu@cczu.edu.cn.ORCID https://orcid.org/0000-0002-9732-1454

Jianwei SunDepartment of Chemistry, The Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong SAR 999077 China sunjw@ust.hk.ORCID https://orcid.org/0000-0002-2470-1077

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Optically active epibromohydrins represent a structurally privileged family of chiral building blocks, yet their asymmetric synthesis remains hampered by a reliance on stoichiometric chemical oxidants and multi-step protocols. Herein, we report an organocatalytic asymmetric electrochemical bromoetherification of allylic tertiary alcohols that constructs these densely functionalized scaffolds in a single operational step. By merging interfacial electrosynthesis with a synergistic chiral phase-transfer catalyst (PTC) and chiral phosphoric acid (CPA) counter anion framework, the high reactivity of electrogenerated Br

Identifiers

PMID42708067

DOI10.1039/d6sc05589c

PMCPMC13549308

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.