ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Polymer-Grafted Cu(II) Metal-Organic Polyhedra as Scalable, Melt-Processable Porous Materials.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The development of porous materials that combine low-temperature meltability with high gas uptake remains a major challenge. Herein, we report Cu-BCN-5, a polymer-grafted Cu(II) metal-organic polyhedron (MOP), as a scalable melt-processable material with intrinsic porosity. This material melts at 44°C while preserving cage integrity and accessible porosity. By overcoming diffusion limitations imposed by the polymer corona during sorption measurements, the material reaches a CO
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