ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Minimal Transport Units Govern Oxygen-Defect Stabilization and Transport for Lightweight Solid Electrolytes.
Xiaohui Li, Yongkang Zheng, Li Yang, Xiaoge Wang, Yuan Gou, Guanqun Cai, Jie Liu, Cheng Li, Kun Lin, Qiang Li and 4 more
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In one paragraphArticle in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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14 authors.
Xiaohui LiFuture Energy Interdisciplinary Center, Key Laboratory of Solid-State Energy Conversion and Storage of Jiangxi Education Department, School of Intelligent Manufacturing and Future Energy, Gannan Normal University, Ganzhou, Jiangxi, P. R. China.
Yongkang ZhengGuangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, P. R. China.
Li YangGuangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, P. R. China.
Yuan GouGuangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, P. R. China.
Guanqun CaiCollege of Chemistry and Molecular Engineering, Beijing National Laboratory for Molecular Science (BNLMS), Peking University, Beijing, P. R. China.
Kun LinBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing, P. R. China.ORCID https://orcid.org/0000-0003-4515-3206 Qiang LiBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing, P. R. China.ORCID https://orcid.org/0000-0003-4259-6984 Xianran XingBeijing Advanced Innovation Center for Materials Genome Engineering, Institute of Solid State Chemistry, University of Science and Technology Beijing, Beijing, P. R. China.ORCID https://orcid.org/0000-0003-0704-8886 Xiaojun KuangFuture Energy Interdisciplinary Center, Key Laboratory of Solid-State Energy Conversion and Storage of Jiangxi Education Department, School of Intelligent Manufacturing and Future Energy, Gannan Normal University, Ganzhou, Jiangxi, P. R. China.ORCID https://orcid.org/0000-0003-2975-9355 Funding
Guangxi Key Research & Development Program GuikeAB25069467Guangxi Natural Science Foundation 2025GXNSFBA069588National Natural Science Foundation of China 22090043National Natural Science Foundation of China 22205017National Natural Science Foundation of China 22575063National Natural Science Foundation of China 22665011
6 · The paper itselfAbstract
Solid electrolytes are central to electrochemical energy technologies, including fuel cells, sensors, catalysis, membrane separation, and electrolyser. However, most established oxide-ion solid electrolytes are built around heavy B-site cations embedded in rigid and highly connected coordination frameworks, leading to widespread high-weight and sluggish ionic transport that is strongly coupled to large-amplitude lattice relaxations. This intrinsic challenge hinders further performance optimization and constrains the rational design of lightweight electrolytes. Herein, we propose a minimal transport unit-based design paradigm that combines simplified structural motifs with light-element chemistry, enabled by the exceptional flexibility of B-O polyhedra in coordination, rotation, deformation, and connectivity. As a proof of concept, Sc
Indexed as
borate oxide‐ion electrolytelocal structuremininal transport unitsNMR spectroscopy and variable‐temperature PDFoxide‐ion transport mechanism
Identifiers
PMID42702921
PMCPMC13547790
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