ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Unlocking Low-Melting-Point and High-Conductivity Molten Salts via High-Entropy Strategy with Demonstration in Thermal Batteries.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The development of advanced molten salt electrolytes for thermal batteries has long been hindered by an intrinsic trade-off between low melting point and high ionic conductivity, posing a fundamental limitation to their performance optimization. To address this challenge, this work reports a high-entropy design strategy that breaks this long-standing constraint by leveraging configurational complexity to simultaneously modulate thermodynamic and transport properties. By constructing a quinary LiF-LiCl-LiBr-KBr-CsBr molten salt system, the introduction of multiple ionic species generates substantial lattice distortion and high configurational entropy, leading to a markedly reduced melting point of 229.5°C and 1.19 S cm
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