ArticleNature communications2026
Electrodeposition-initiated, self-catalyzed growth of 2D amorphous Fe-group metal-boron alloy mesoporous films.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Two-dimensional mesoporous amorphous metallic films, particularly those based on earth-abundant Fe-group metals (Ni, Co, Fe), are highly promising for various applications due to their high surface area, structural isotropy, and abundant undercoordinated sites. However, synthesizing continuous Fe-group amorphous metallic films with well-defined mesoporosity under mild conditions remains a challenge. Here, we develop an electrodeposition-initiated, self-catalyzed electroless growth strategy, enabling the synthesis of composition-tunable (from binary to quaternary) amorphous Fe-group metal-boron (M-B) mesoporous films (MFs) on various conductive substrates. This approach decouples the nucleation and growth stages, allowing precise control over film thickness, composition, and mesostructure. Thickness-time measurements suggest a self-accelerating growth process, whereas finite-element simulations indicate that substrate-dependent electric-field distributions modulate the nucleation and growth morphology. The synthesized multimetallic amorphous Ni-Co-Fe-B MF demonstrates high oxygen evolution performance and durability in alkaline simulated seawater, making them promising candidates for practical applications. Theoretical insights reveal preferential OH
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