Evidence map›Paper›PMID 42670486›Full record

ArticleChemical science2026

Aggregated-state arylborane-pillar[5]arenes: a new three-in-one method for the modulation of circularly polarized luminescence.

Yuting Xue, Yu Tian, Ruiquan Li, Xuanyi Bie, Haoyuan Luo, Bingjun Li, Niu Zhang, Pangkuan Chen

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Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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2 · The registry

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3 · Its place in the literature

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4 · The record

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5 · Who and what money

Authors and funding

8 authors.

Yuting XueKey Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China Beijing 102488 China pangkuan@bit.edu.cn.
Yu TianKey Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China Beijing 102488 China pangkuan@bit.edu.cn.
Ruiquan LiKey Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China Beijing 102488 China pangkuan@bit.edu.cn.
Xuanyi BieKey Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China Beijing 102488 China pangkuan@bit.edu.cn.
Haoyuan LuoKey Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China Beijing 102488 China pangkuan@bit.edu.cn.
Bingjun LiKey Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China Beijing 102488 China pangkuan@bit.edu.cn.
Niu ZhangAnalysis & Testing Centre, Beijing Institute of Technology of China Beijing 102488 China niuzhang2019@bit.edu.cn.
Pangkuan ChenKey Laboratory of Cluster Science of the Ministry of Education, Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering of the Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology of China Beijing 102488 China pangkuan@bit.edu.cn.ORCID https://orcid.org/0000-0002-8940-7418

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Although chiroptical macrocyclic systems are highly studied in supramolecular chemistry and materials science, it remains a substantial challenge to simultaneously achieve high emission efficiency and a strong circularly polarized luminescence (CPL) dissymmetry factor. Herein, we report a molecular design strategy that integrates aggregation-induced emission (AIE), heteroatom incorporation, and symmetry engineering to modulate the chiroptical performance of planar chiral pillar[5]arene luminogens. In these modular chiral systems of arylborane-pillar[5]arenes (1-4) functionalized with classical tetraphenylethylene (TPE) and BN-isostere tetraarylaminoborane (BN-TPE), the heteroatom-regulated excited-state electronic structures and BN dipole-induced symmetry perturbation are synergistically coupled with AIE-active emissions, enabling the simultaneous enhancement of fluorescence efficiency and CPL performance. Compared with the carbon-based parent 1, both 2 and 4 exhibit highly enhanced chiroptical properties with an aggregated-state emission quantum yields (

Identifiers

PMID42670486
PMCPMC13526487

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.