ArticleNature communications2026
Breaking the activity-stability trade-off via dual-mechanism induced by rare earths for lasting seawater electrolysis.
Article in Nature communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Triggering the adsorbate evolution and lattice oxygen mechanisms coupled path holds promise for overcoming the activity-stability trade-off of oxygen evolution reaction (OER). However, achieving precise regulation and activation of multiple OER pathways via 3d-metal modification strategy remains challenging due to the external effects of crystal fields and coordination environments. Herein, we propose an atomic-dispersed rare earth substitution strategy to construct a spatially partitioned reaction mechanism, and achieve dual activation between adsorbate evolution and lattice oxygen mechanisms. The strong shielding effect of 5 s/5p electrons in RE significantly reduces the influence of the external environment on the 4 f orbitals, thereby enhancing the controllability of the reaction pathway. The optimized Sm-NiMoO
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