Janus Reactivity of a Mononuclear Non-Heme Iron(III)-Peroxo Complex Toward Indole Oxidation.

Wenjuan Zhu, Peng Wu, Binju Wang, Kallol Ray, Wonwoo Nam

Abstract read

In one paragraph

Article in Angewandte Chemie (International ed. in English), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

Authors and funding

5 authors.

Wenjuan ZhuDepartment of Chemistry and Nano Science, Ewha Womans University, Seoul, South Korea.ORCID https://orcid.org/0000-0003-4316-370X

Peng WuState Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan, P. R. China.ORCID https://orcid.org/0009-0008-5472-5847

Binju WangKey Laboratory of Physical Chemistry of Solid Surfaces and Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, P. R. China.

Kallol RayInstitut für Chemie, Humboldt-Universität Zu Berlin, Berlin, German.ORCID https://orcid.org/0000-0003-2074-8844

Wonwoo NamDepartment of Chemistry and Nano Science, Ewha Womans University, Seoul, South Korea.ORCID https://orcid.org/0000-0001-8592-4867

Funding

Henan Center for Outstanding Overseas Scientists GZS2024020 to W.NNational Natural Science Foundation of China 22403055 to P.WNRF of Korea RS-2021-NR059914NRF of Korea RS-2023-NR121124

6 · The paper itself

Abstract

Indole oxidation reaction is a pivotal process in organic chemistry, playing a crucial role in the synthesis of various natural products and pharmaceuticals. To-date, indole oxidation is limited to heme enzymes and synthetic iron porphyrin compounds. Herein, we demonstrate its efficient execution in a nonheme iron system. We report the oxidation of a broad range of indole substrates by a mononuclear nonheme iron(III)-peroxo complex, [Fe

Indexed as

Coordination ComplexesFerric CompoundsIndolesHemeMolecular StructureOxidation-ReductionCoordination ComplexesFerric CompoundsHemeindoleIndolesbifurcation reaction pathwayselectrophilic additionindole oxidationIron(III)‐peroxoN─H hydrogen atom abstraction

Identifiers

PMID42658826

DOI10.1002/anie.1874384

PMCPMC13676403

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.