ArticleChemical science2026
Naphthalimide-fused BODIPYs
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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9 authors.
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Abstract
Near-infrared (NIR) n-type organic semiconductors with low-lying LUMO levels are essential building blocks for advanced optoelectronics, yet their development is hindered by laborious multi-step synthesis, insufficient electron affinity and limited stability. Herein, we report the precise synthesis and optoelectronic properties of a series of naphthalimide (NMI)-fused BODIPY derivatives as near-infrared absorbing n-type organic semiconductors, accessed through a palladium-catalyzed one-pot quadruple C-H activation strategy that constructs the fused conjugated framework in a single step. This annulation extends the large π-conjugated system and enables a favorable face-to-face molecular stacking in the crystalline state. The resulting dyes exhibit efficient NIR emission (
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