ArticleMolecules (Basel, Switzerland)2026
Catalytic Ring Opening of Epoxides by Metal Triflates: Influence of a Pending Olefin.
Article in Molecules (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Lewis acid-catalyzed epoxide openings efficiently promote intramolecular cyclizations forming complex oxygenated frameworks. Herein, we investigated the reactivity of epoxyolefins under catalytic conditions using various metal triflates. The study focuses on the competition between epoxide isomerization and intramolecular cyclization involving a pendant olefin. Screening of several metal triflates revealed that Lewis superacids, particularly Bi(OTf)
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