Evidence map›Paper›PMID 42649591›Full record

ArticleMacromolecular rapid communications2026

Polymeric Polyaldehyde Approach to Develop Robust Dynamic Covalent Adaptive Polyimine Networks.

Subrata Dolui, Sofia Nieves Casillas-Popova, Seung Ki Lee, Sun Ju Kim, Hira Rasheed, Zhibin Ye, Minsoo P Kim, Hyun Wook Jung, Jung Kwon Oh

Abstract read
In one paragraph

Article in Macromolecular rapid communications, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Subrata DoluiDepartment of Chemistry and Biochemistry, Concordia University, Montreal, Quebec, Canada.
Sofia Nieves Casillas-PopovaDepartment of Chemistry and Biochemistry, Concordia University, Montreal, Quebec, Canada.
Seung Ki LeeDepartment of Chemical and Biological Engineering, Korea University, Seoul, Republic of Korea.
Sun Ju KimDepartment of Chemical Engineering, Sunchon National University, Suncheon-si, Jeollanam-do, Republic of Korea.
Hira RasheedDepartment of Chemistry and Biochemistry, Concordia University, Montreal, Quebec, Canada.
Zhibin YeDepartment of Chemical and Materials Engineering, Concordia University, Montreal, Quebec, Canada.ORCID https://orcid.org/0000-0002-3738-7072
Minsoo P KimDepartment of Chemical Engineering, Sunchon National University, Suncheon-si, Jeollanam-do, Republic of Korea.ORCID https://orcid.org/0000-0003-0285-3253
Hyun Wook JungDepartment of Chemical and Biological Engineering, Korea University, Seoul, Republic of Korea.ORCID https://orcid.org/0000-0001-8395-2573
Jung Kwon OhDepartment of Chemistry and Biochemistry, Concordia University, Montreal, Quebec, Canada.ORCID https://orcid.org/0000-0002-4220-308X

Funding

Natural Science and Engineering Research Council
6 · The paper itself

Abstract

Polyimine-based covalent adaptive networks crosslinked with Schiff bases (PI-CANs) have been developed as effective building blocks to construct advanced polymeric materials possessing reprocessability, self-healability, and sustainability. Most approaches to fabricate PI-CANs involve the synthesis and use of small molecule polyaldehydes. Herein, we report a versatile approach exploring the synthesis of polymeric polyaldehydes (PP-CHO) with a polyacrylate backbone bearing pendant aldehyde groups to develop self-healable, reprocessable polyacrylate-PI hybrid CANs. The approach centers on the synthesis of well-defined poly(2-hydroxyethyl acrylate) bearing aldehyde pendants (PHEA-CHO) by a photo-indued reversible deactivation radical polymerization,(Photo-RDRP) followed by post-polymerization modification. The PHEA-CHO is highly reactive to an aliphatic diamine, enabling the fabrication of transparent, integrated, dynamic PHEA-PI hybrid CAN films. They exhibit lower activation energy (E

Indexed as

AldehydesPolymersAcrylatesMolecular StructurePolymerizationSchiff Bases2-hydroxyethyl acrylateAcrylatesAldehydesPolymersSchiff Basesatom transfer radical polymerizationcovalent adaptive networkspolyiminepolymeric polyaldehydesreprocessingreversible deactivation radical polymerizationschiff‐baseself‐healing

Identifiers

PMID42649591
PMCPMC13681340

What OpenQuestion holds

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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.