Bioinspired cooperative bimetallic activation of an isocyanide by a Cu(I)-Mo(VI) system.

A M Buddhika Chandima, P A S N P Jayawardena, Teodore J Melnyczuk-Gould, Cassandra L Ward, Stanislav Gelman-Tropp, Dmitri Gelman, Richard L Lord, Stanislav Groysman

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In one paragraph

Article in Chemical communications (Cambridge, England), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

A M Buddhika ChandimaDepartment of Chemistry, Wayne State University, 5101 Cass Ave., Detroit, MI 48202, USA. groysman@wayne.edu.

P A S N P JayawardenaDepartment of Chemistry, Wayne State University, 5101 Cass Ave., Detroit, MI 48202, USA. groysman@wayne.edu.

Teodore J Melnyczuk-GouldDepartment of Chemistry, Wayne State University, 5101 Cass Ave., Detroit, MI 48202, USA. groysman@wayne.edu.ORCID http://orcid.org/0009-0009-6304-053X

Cassandra L WardLumigen Instrument Center, Wayne State University, 5101 Cass Avenue, Detroit, Michigan 48202, USA.ORCID http://orcid.org/0000-0001-6736-6769

Stanislav Gelman-TroppInstitute of Chemistry, The Hebrew University, Edmond Safra Campus, Givat Ram, 91904 Jerusalem, Israel.

Dmitri GelmanInstitute of Chemistry, The Hebrew University, Edmond Safra Campus, Givat Ram, 91904 Jerusalem, Israel.

Richard L LordDepartment of Chemistry, Grand Valley State University, 1 Campus Drive, Allendale, Michigan 49401, USA.ORCID http://orcid.org/0000-0001-6692-0369

Stanislav GroysmanDepartment of Chemistry, Wayne State University, 5101 Cass Ave., Detroit, MI 48202, USA. groysman@wayne.edu.ORCID http://orcid.org/0000-0003-3578-7985

Funding

Library Synthesis and Screening of Eu(II)-Based Contrast AgentsR01EB027103 · NIBIB · WAYNE STATE UNIVERSITY · PI ALLEN, MATTHEW J · 2019 to 2022

$1.4M

NIBIB NIH HHS R01 EB027103

6 · The paper itself

Abstract

Mo-Cu CODH catalyzes cooperative bimetallic activation of CO and isocyanides, with Cu(I) likely activating the substrate toward nucleophilic attack by Mo(VI)-oxo. We report a synthetic heterobimetallic Cu(I)-Mo(VI) functional model, in which Cu(I) activates xylyl isocyanide, whereas (Et

Identifiers

PMID42647040

DOI10.1039/d6cc04392e

PMCPMC13512062

What OpenQuestion holds

Textmetadata

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.