ArticleGels (Basel, Switzerland)2026
Mesoporous Confinement of Fluorescent Dyes in Ultra-Transparent Silica Aerogel Films via Tailored Sol-Gel Kinetics.
Article in Gels (Basel, Switzerland), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Silica aerogel films are highly promising matrices for advanced optical applications, yet balancing ultra-high transmittance with structural stability during functionalization remains a critical challenge. Directly incorporating organic dyes often leads to aggregation and severe photodegradation, necessitating a robust host-guest encapsulation strategy. Herein, we report the fabrication of ultra-transparent, fluorescent silica aerogel films via precisely tailored acid/base two-step sol-gel kinetics and dip-coating. The optimized pure silica matrix achieves a peak visible transmittance of 97.4% and sub-nanometer surface smoothness (RMS = 276.7 pm). By utilizing this pristine network, Rhodamine 6G (Rh6G) and Rhodamine B (RhB) dyes were effectively confined within the amorphous mesoporous pores. Notably, RhB exhibited superior matrix integration, indicated by an H4 hysteresis loop transition and a significantly reduced pore volume (0.019 cm
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