ArticleNature materials2026
Crystal nucleation and growth in high-entropy alloys revealed by atomic electron tomography.
Article in Nature materials, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Three-dimensional network of multi-fold twins enabled by geometrically necessary amorphous zones.Nature communications · 2025Article
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Authors and funding
13 authors.
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No grant is acknowledged in the PubMed record.
Abstract
High-entropy alloys combine multiple principal elements and can exhibit exceptional mechanical properties and catalytic activity. However, how they crystallize remains poorly understood because early nuclei are small, transient and chemically complex. Here we advance atomic electron tomography to determine the three-dimensional atomic structures and local chemical order of 8,160 high- and medium-entropy alloy nuclei. We find that nucleation proceeds through gradient ordering, in which structural order is highest at the core, decreases smoothly towards the boundary and is coupled to local chemical order. Most nuclei coalesce with nearly aligned crystal lattices, whereas a minority form twin boundaries. We develop the gradient nucleation pathways model, which generalizes classical nucleation theory by incorporating spatially varying structural order within each nucleus. The model captures diffuse, partially ordered nuclei, recovers classical nucleation theory in the sharp-interface limit and reveals multiple intermediate states. These results provide an atomistic framework for understanding crystal nucleation and growth across a broad range of materials.
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42642484What OpenQuestion holds
Registered trials
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