ReviewChemistry, an Asian journal2026
Recent Advances in Dual Palladium Photoredox Catalysis.
Review in Chemistry, an Asian journal, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Dual palladium/photoredox catalysis has emerged as a versatile platform for constructing complex molecular architectures. These systems enable a broad range of transformations by integrating palladium's well-established roles in C─H activation and cross-coupling with the single-electron transfer capabilities of photocatalysts. Recent developments (2022-2026) in dual Pd/photoredox catalysis, from a mechanistic standpoint, reveal two interconnected activation pathways: conventional Pd(0)/Pd(II) catalytic cycles and photoredox-driven radical generation. This review focuses on mechanistic insights governing atom- and radical-transfer processes, encompassing diverse transformations such as C─C and C─X bond formation as well as late-stage functionalization. Furthermore, it provides a conceptual framework that distinguishes dual Pd/photoredox catalysis from traditional palladium-only or photocatalytic approaches by analyzing the interplay between these two catalytic regimes.
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