Evidence map›Paper›PMID 42639577›Full record

ArticleChemical science2026

An anionic nickel-aluminium dihydride complex exhibiting cooperative catalytic behaviour.

Roel L M Bienenmann, Luca Vedani, Andryj M Borys, Wilhelm Klein, Eva Hevia

Abstract read
In one paragraph

Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Divergent construction of Ni and Fe-Al-H assemblies.Chemical communications (Cambridge, England) · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Roel L M BienenmannDepartment for Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern Freiestrasse 3 Bern 3012 Switzerland eva.hevia@unibe.ch.ORCID https://orcid.org/0000-0001-6050-6212
Luca VedaniDepartment for Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern Freiestrasse 3 Bern 3012 Switzerland eva.hevia@unibe.ch.ORCID https://orcid.org/0009-0007-8873-2685
Andryj M BorysDepartment for Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern Freiestrasse 3 Bern 3012 Switzerland eva.hevia@unibe.ch.ORCID https://orcid.org/0000-0001-8437-2562
Wilhelm KleinTechnical University of Munich, Catalysis Research Centre Ernst-Otto-Fischer-Straße 1 85748 Garching Germany.ORCID https://orcid.org/0000-0002-6351-9921
Eva HeviaDepartment for Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern Freiestrasse 3 Bern 3012 Switzerland eva.hevia@unibe.ch.ORCID https://orcid.org/0000-0002-3998-7506

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In nickel catalysis, aluminium additives have found ample use in aiding the activation and functionalisation of strong bonds. However, despite the common occurrence of both nickel hydride and aluminium hydride species in homogeneous catalysis, heterobimetallic NiAl hydride complexes have only been scarcely studied. Moreover, uses of such complexes as catalysts are extremely rare and their potential to enable cooperative reactivity remains largely underexplored. Opening new ground in this area here we report a novel and stable low valent NiAl dihydride 'ate' complex obtained by reacting a Ni(0) tris(olefin) precursor with LiAlH

Identifiers

PMID42639577
PMCPMC13502330

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.