ArticleChemical science2026
Visible-light-promoted nickel-catalyzed cross-coupling of B-iodocarboranes with styrenes.
Article in Chemical science, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
5 authors.
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Abstract
A visible-light-promoted, nickel-catalyzed cross-coupling reaction of B-iodocarboranes with styrenes has been developed, enabling efficient and site-divergent alkenylation of carboranes under mild conditions. The reaction exhibits broad substrate scope, accommodating a wide range of styrene derivatives bearing various electronic and steric properties, as well as ethylene, to afford the corresponding alkenylated products in good to excellent yields. This work provides a practical and sustainable approach for carborane functionalization under ambient conditions and expands the synthetic utility of carboranyl radicals in transition metal-catalyzed Heck-type cross-coupling reactions.
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