ArticleNature materials2026
Flux-mediated ligand exchange restructures metal-organic framework glasses.
Article in Nature materials, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Melt-quenched glasses derived from metal-organic frameworks (MOFs) combine the processability of glasses with the modularity and microporosity of MOFs, yet remain structurally and functionally less diverse than crystalline analogues. Here we show that the chelating ligand 1,10-phenanthroline acts as an organic flux that lowers the glass transition temperature of selected MOFs and induces ligand exchange during melting, thereby enabling control over local coordination and global topology in MOF glasses. In Co
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