ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Precisely Regulating 2.45 s Pure Blue Room-Temperature Phosphorescence via Supramolecular Coordination.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Achieving tunable blue room-temperature phosphorescence (BRTP) emission faces forbidden challenges due to difficulties in generating high-energy triplet excitons and their sensitivity. Herein, a covalently crosslinked purely organic material (BOP@BA) is prepared from boric acid (BA) and 3,5-dicarboxyphenylboronic acid (BOP) via a simple dehydration reaction. This material exhibits pure deep blue room-temperature phosphorescence (RTP) with a lifetime of 2.45 s. Unlike individual BA or BOP, dehydrated BOP@BA exhibits a hypsochromic shift to 415 nm, yielding a purely deep-blue RTP. Meanwhile, the formed covalent skeleton protects the high-energy triplet excitons from nonradiative deactivation, thereby elongating the lifetime to 2.45 s. Significantly, lanthanide ions (Ln
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