ArticleOrganic letters2026
SESMic: A Reagent for the Synthesis of 5-Membered Heteroaryl Masked Sulfinates.
Article in Organic letters, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Authors and funding
3 authors.
Funding
Abstract
Sulfur(VI) functionalities are found in numerous value-added products; however, methods for the synthesis of heterocyclic sulfonyl fluorides are limited. 4-Substituted sulfonyl fluoride azoles could be useful synthons in drug discovery and biochemical applications due to their enhanced stability derived from their electron-rich nature. In this study, we develop an isocyanide reagent, SESMic, that contains a sulfinate protecting group allowing for synthesis of a variety of heterocycles followed by sulfinate unmasking and further functionalization. SESMic specifically allows access to 4-substituted sulfonyl fluorides, which were shown to be more stable than their aryl congeners.
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Registered trials
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