ArticleSmall (Weinheim an der Bergstrasse, Germany)2026
Layered Nickel-HHTP Networks for Efficient Chemiresistive Sensing of CH
Article in Small (Weinheim an der Bergstrasse, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The synthesis and single-crystal structural elucidation of Ni-HHTP are reported for the first time, achieved from crystals of sufficient size for electron diffraction analysis. These studies reveal that the crystal structure of Ni-HHTP alternates between radical-rich and closed-shell layers along the c-axis, forming a periodic, sandwich-like architecture. The Ni-HHTP coordination pattern differs between these two types of alternating 2D-networks, reflecting distinct electronic environments. Water molecules are either coordinated to the framework or accommodated within the lattice, giving rise to a swelling effect with increasing water content. The well-defined structure enables direct correlation between framework architecture and function. Ni-HHTP exhibits a distinct chemiresistive response toward CO
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