ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2026
Bidirectional Soft Catalysts for Improved Power Performance of Li-S Batteries.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
Lithium-sulfur (Li-S) batteries are attractive for next-generation energy storage owing to their high theoretical energy density and low cost, yet their practical performance is limited by sluggish redox kinetics. Here, we introduce a soft catalyst in which a polymer-metal complex is directly integrated into the binder, creating a catalytically active microenvironment that enables efficient and bidirectional sulfur catalysis. A polyvinyl alcohol (PVA) scaffold stabilizes metal ions through chelation with the electron-donating -OH groups of PVA, forming homogeneously distributed catalytic domains in the sulfur cathode. Among the systems investigated, PVA-Cu exhibits the highest catalytic activity, arising from optimal sulfur binding energies, Cu-S d-p hybridization, and additional electronic states near the Fermi level. As a result, the PVA-Cu cells deliver high capacities at 3 mg cm
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