ArticleACS omega2026
Sustainable Dual Cross-Linking Strategy of Lignin with Oxazoline-Modified Nitrile Rubber for Mechanically Robust Elastomeric Composites.
Article in ACS omega, 2026. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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7 authors.
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Abstract
Lignin, the most abundant aromatic biopolymer in nature, represents a highly promising renewable feedstock for the development of value-added polymer composites. However, its inherently poor compatibility with elastomeric matrices limits its effective utilization in high-performance and multifunctional lignin-filled systems. In this study, we report a cost-effective and sustainable cross-linking strategy to compatibilize and chemically integrate lignin within an acrylonitrile butadiene rubber (NBR) matrix through interfacial oxazoline chemistry, without the use of conventional sulfur- or peroxide-based curing agents. A small fraction of the pendant nitrile (-CN) groups of NBR were selectively converted into oxazoline rings via reactive melt compounding. Furthermore, interfacial compatibility was enhanced by incorporating 4 phr ZnCl
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